Pure semiconductors (like Silicon or Germanium) are very poor conductors of electricity. To make them useful, we 'dope' them with impurities. Depending on the impurity added, we get two types of extrinsic semiconductors: N-Type and P-Type.
N-Type: Pentavalent impurity, Majority carriers = Electrons.
P-Type: Trivalent impurity, Majority carriers = Holes.
Neutrality: Both N-type and P-type semiconductors are electrically NEUTRAL overall. The 'N' and 'P' just refer to the majority charge carriers.
| Feature | N-Type | P-Type |
|---|---|---|
| Impurity Added | Pentavalent (Group 15) | Trivalent (Group 13) |
| Majority Carriers | Electrons | Holes |
| Minority Carriers | Holes | Electrons |
| Energy Level | Donor level is near conduction band | Acceptor level is near valence band |
An N-type semiconductor is doped with pentavalent impurities and its main charge carriers are electrons. A P-type semiconductor is doped with trivalent impurities and its main charge carriers are holes.
A trivalent impurity (like Boron or Gallium, which has 3 valence electrons) is added to make a P-type semiconductor.
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