Study Guides/Chemistry/Permanent Hardness Cannot be Removed By
Study Guide · Chemistry

Permanent Hardness of Water

Hard water contains high levels of dissolved minerals. In Class 11 Chemistry (Hydrogen chapter), understanding the difference between temporary and permanent hardness is crucial.

Question (Click to Flip)

What causes temporary hardness?

Answer

Temporary hardness is caused by dissolved bicarbonates (hydrogen carbonates) of calcium and magnesium: Ca(HCO₃)₂ and Mg(HCO₃)₂.

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Key Facts

Hard water does not lather easily with soap, leading to wastage of soap and the formation of scum. It also causes scaling in boilers and pipes.

What is Permanent Hardness?

Permanent hardness of water is caused by the presence of soluble chlorides and sulphates of calcium and magnesium (e.g., CaCl₂, MgCl₂, CaSO₄, MgSO₄).

It CANNOT be removed by:

Permanent hardness CANNOT be removed by BOILING.

Boiling only removes temporary hardness (which is caused by bicarbonates of Ca and Mg). When you boil water with permanent hardness, the chlorides and sulphates do not precipitate out; they remain dissolved.

How CAN it be removed?

To remove permanent hardness, chemical methods are required:

  1. Washing Soda Method: Adding washing soda (Na₂CO₃) reacts with the calcium/magnesium chlorides to form insoluble carbonates which precipitate out. CaCl₂ + Na₂CO₃ → CaCO₃(ppt) + 2NaCl
  2. Calgon's Method: Using sodium hexametaphosphate (Calgon) to form complex soluble ions that do not cause hardness.
  3. Ion-Exchange Method: Using zeolite or synthetic resins to exchange Ca²⁺/Mg²⁺ ions with Na⁺ or H⁺ ions.

Questions and Answers

What causes temporary hardness?+

Temporary hardness is caused by dissolved **bicarbonates (hydrogen carbonates)** of calcium and magnesium: Ca(HCO₃)₂ and Mg(HCO₃)₂.

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