Study Guides/Chemistry/Flocculated and Deflocculated Suspension — Difference
Study Guide · Chemistry

Flocculated and Deflocculated Suspension — Meaning and Difference

A pharmaceutical suspension is a liquid preparation in which fine solid particles of a medicine are dispersed in a liquid in which they do not dissolve. Over time, these particles settle down. Depending on how the particles behave, suspensions are of two types — flocculated and deflocculated. In a flocculated suspension the particles join into loose clusters called flocs, while in a deflocculated suspension the particles remain separate. Understanding the difference between them is important in pharmaceutics because it affects the stability and quality of the suspension.

Question (Click to Flip)

What is the difference between flocculated and deflocculated suspension?

Answer

In a flocculated suspension the particles join into loose clusters (flocs) that settle quickly but redisperse easily and do not form a hard cake. In a deflocculated suspension the particles remain separate, settle slowly, but form a hard, closely packed cake that is difficult to redisperse (caking). So flocculated suspensions settle fast but shake back easily, while deflocculated ones settle slowly but tend to cake.

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Key Facts

A suspension has solid particles dispersed in a liquid in which they do not dissolve.

Flocculated suspension: particles form loose clusters called flocs.

Deflocculated suspension: particles remain separate.

Flocculated suspensions settle fast but redisperse easily and do not cake.

Deflocculated suspensions settle slowly but form a hard cake (caking).

In flocculated suspensions the supernatant becomes clear quickly.

Controlled flocculation is used to get the advantages of both types.

Flocculated Suspension

In a flocculated suspension, the suspended particles are loosely joined together to form light, fluffy clusters called 'flocs'.

Features: • Particles form loose aggregates (flocs). • The flocs settle rapidly because they are larger. • The sediment formed is loose and fluffy. • The sediment can be redispersed easily by shaking. • No hard cake is formed. • The supernatant liquid (the clear liquid above) becomes clear quickly.

Main drawback: because the particles settle fast, the suspension may look unattractive (it appears to separate quickly), but it is easy to shake back into a uniform mixture.

Deflocculated Suspension

In a deflocculated suspension, the particles stay separate and do not join into flocs.

Features: • Particles remain as separate individual particles. • They settle slowly because they are small. • The sediment formed is closely packed and hard. • The sediment forms a hard 'cake' that is very difficult to redisperse — this is called caking. • The supernatant liquid remains cloudy for a long time.

Main drawback: although it settles slowly and looks good at first, once the particles settle they form a hard cake at the bottom that cannot be shaken back into suspension, which spoils the product.

Difference Between Flocculated and Deflocculated Suspension

Flocculated Suspension: • Particles form loose flocs • Rate of settling is fast • Sediment is loose and fluffy • Easily redispersed on shaking • No caking (no hard cake) • Supernatant becomes clear quickly

Deflocculated Suspension: • Particles remain separate • Rate of settling is slow • Sediment is hard and closely packed • Difficult to redisperse (forms a cake) • Caking occurs • Supernatant stays cloudy for long

In practice, a good suspension is often made 'controlled flocculated' to get the benefits of both — slow, even settling without hard caking.

Questions and Answers

What is the difference between flocculated and deflocculated suspension?+

In a flocculated suspension the particles join into loose clusters (flocs) that settle quickly but redisperse easily and do not form a hard cake. In a deflocculated suspension the particles remain separate, settle slowly, but form a hard, closely packed cake that is difficult to redisperse (caking). So flocculated suspensions settle fast but shake back easily, while deflocculated ones settle slowly but tend to cake.

What is a flocculated suspension?+

A flocculated suspension is one in which the suspended particles are loosely joined together to form light, fluffy clusters called flocs. These flocs settle rapidly, form a loose sediment, do not cake, and can be easily redispersed by shaking. The supernatant liquid becomes clear quickly.

What is caking in a deflocculated suspension?+

Caking is the formation of a hard, closely packed sediment at the bottom of a deflocculated suspension. Because the separate particles settle slowly and pack tightly, they form a hard 'cake' that cannot be shaken back into the liquid. Caking is undesirable because it spoils the suspension.

Which is better, a flocculated or deflocculated suspension?+

A flocculated suspension is generally preferred in pharmacy because it does not form a hard cake and can be easily redispersed, even though it settles quickly. To get the advantages of both, a 'controlled flocculated' suspension is often prepared, which settles slowly and evenly without forming a hard cake.

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