Study Guides/Chemistry/Mendeleev's Periodic Table
Study Guide · Chemistry

Describe Mendeleev's Periodic Table

In 1869, Russian chemist Dmitri Mendeleev created the most successful early version of the Periodic Table. His work laid the foundation for the modern table we use today.

Question (Click to Flip)

What is Mendeleev's periodic law?

Answer

Mendeleev's periodic law states that the physical and chemical properties of elements are a periodic function of their atomic masses.

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Key Facts

Basis: Increasing Atomic Mass.

Law: Properties are periodic functions of atomic mass.

Genius Move: Left blank spaces for undiscovered elements (predicted Gallium/Germanium).

Flaws: Position of Hydrogen, couldn't explain Isotopes, Cobalt/Nickel inversion.

Mendeleev's Periodic Law

Mendeleev's entire table was based on one fundamental law: 'The properties of elements are the periodic functions of their atomic masses.'

This meant that if you arrange elements in increasing order of their atomic mass, elements with similar chemical properties will appear at regular intervals (periodically).

Main Features of the Table

  1. Groups and Periods: He arranged the 63 known elements into vertical columns called Groups (I to VIII) and horizontal rows called Periods (1 to 6).
  2. Chemical Formulae basis: He relied heavily on the formulae of hydrides and oxides formed by elements to group them together.

Merits (Achievements)

  1. Predicting New Elements: Mendeleev boldly left blank spaces in his table for elements that had not been discovered yet! He named them Eka-Boron, Eka-Aluminium, and Eka-Silicon. Years later, Scandium, Gallium, and Germanium were discovered and perfectly matched his predicted properties.
  2. Correcting Atomic Masses: He corrected the accepted atomic masses of elements like Beryllium based on their position.
  3. Noble Gases: When Noble Gases were later discovered, they could be placed in a new separate group without disturbing the existing table.

Limitations (Failures)

  1. Position of Hydrogen: He could not give a fixed position to Hydrogen (it acted like both alkali metals and halogens).
  2. Isotopes: Since isotopes have different atomic masses but identical chemical properties, they violated his rule of placing elements strictly by mass.
  3. Wrong Order: In a few places, an element with a slightly higher atomic mass was placed before a lower one to maintain chemical groupings (e.g., Cobalt 58.9 came before Nickel 58.7).

Questions and Answers

What is Mendeleev's periodic law?+

Mendeleev's periodic law states that the physical and chemical properties of elements are a periodic function of their atomic masses.

What was the greatest achievement of Mendeleev's periodic table?+

His greatest achievement was predicting the existence and properties of undiscovered elements. He left blank spaces for them (like Eka-Aluminium), which were later discovered (Gallium) and matched his predictions exactly.

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