Study Guides/Chemistry/Inner Transition Elements
Study Guide · Chemistry

Inner Transition Elements — f-Block Elements

The Inner Transition Elements are elements in which the last electron enters the f-subshell. They are also called f-block elements and are placed separately at the bottom of the Periodic Table in two horizontal rows.

Question (Click to Flip)

What is Lanthanoid Contraction?

Answer

As you move across the lanthanide series, the atomic radii decrease gradually due to poor shielding by f-electrons. This steady decrease in size is called Lanthanoid Contraction. It has a major effect on the properties of elements following the lanthanides (like Hf, Ta, W).

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Key Facts

India has one of the world's largest reserves of Thorium (an actinide) in its coastal sands (e.g., Kerala's Monazite sands). India's three-stage nuclear programme relies heavily on Thorium as a future fuel.

Two Series of Inner Transition Elements

1. Lanthanides (4f series):

  • Elements from Lanthanum (La, Z=57) to Lutetium (Lu, Z=71) — 14 elements
  • General electron configuration: [Xe] 4f¹⁻¹⁴ 5d⁰⁻¹ 6s²
  • Also called Rare Earth Elements (though not actually rare)
  • All are silvery-white metals with similar properties (making them difficult to separate)
  • Used in: colour TV tubes, lasers, magnets (Nd-Fe-B magnets — strongest permanent magnets)

2. Actinides (5f series):

  • Elements from Actinium (Ac, Z=89) to Lawrencium (Lr, Z=103) — 14 elements
  • General electron configuration: [Rn] 5f¹⁻¹⁴ 6d⁰⁻¹ 7s²
  • All actinides are radioactive (unlike most lanthanides)
  • Most actinides beyond Uranium (Z=92) are synthetic (man-made) elements
  • Used in: nuclear reactors (Uranium, Thorium), nuclear weapons (Plutonium)

Why Placed Separately?

If lanthanides and actinides were placed in the main body of the periodic table, it would become too wide (32 columns wide) to fit on a standard page. So they are traditionally extracted and shown at the bottom. Their position in the table is actually after Group 2 (alkaline earth metals).

Questions and Answers

What is Lanthanoid Contraction?+

As you move across the lanthanide series, the atomic radii decrease gradually due to poor shielding by f-electrons. This steady decrease in size is called **Lanthanoid Contraction**. It has a major effect on the properties of elements following the lanthanides (like Hf, Ta, W).

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