For a complete thermodynamic cycle, the internal energy change is zero (ΔU = 0) because the system returns to its initial state. By the first law of thermodynamics, the net heat supplied equals the net work done by the system: Q_net = W_net. The net work done in a cycle equals the area enclosed by the P-V diagram.
For a complete thermodynamic cycle, ΔU = 0 (internal energy returns to initial value).
By the first law: Q_net = W_net for a complete cycle.
Net work done = area enclosed by the P-V diagram loop.
Clockwise cycle on P-V diagram → positive net work (heat engine).
Anticlockwise cycle on P-V diagram → negative net work (refrigerator/heat pump).
Heat supplied (Q_absorbed) = W_net + Q_rejected.
Thermal efficiency = W_net / Q_absorbed.
First Law: ΔU = Q − W (or Q = ΔU + W)
For a complete cycle:
Applying the first law: 0 = Q_net − W_net Q_net = W_net
This means:
Conclusion: To find the total heat supplied in a complete cycle, calculate the area enclosed by the cycle on the P-V diagram.
Work done by gas during a process = Area under the P-V curve
For a complete cycle:
For a rectangular cycle (simple example): If pressure goes from P₁ to P₂ and volume goes from V₁ to V₂: W_net = (P₂ − P₁)(V₂ − V₁)
For a circular or irregular cycle: W_net = Area of the closed loop on P-V diagram
Since Q_net = W_net for a complete cycle: Heat supplied = Area of the P-V loop
In a complete cycle:
For a heat engine (clockwise cycle): Efficiency η = W_net / Q_absorbed = 1 − Q_rejected/Q_absorbed
For a refrigerator (anticlockwise cycle): COP = Q_cold / W_net = Q_cold / (Q_hot − Q_cold)
Important: 'Heat supplied' usually refers to Q_absorbed (heat added to the system in the cycle).
For a complete cycle, ΔU = 0, so by the first law (Q = ΔU + W), the net heat supplied equals the net work done: Q_net = W_net. The net work equals the area enclosed by the cycle on the P-V diagram.
Internal energy (U) is a state function — it depends only on the state of the system, not the path taken. In a complete cycle, the system returns to its initial state (same temperature, pressure, and volume), so the change in internal energy ΔU = U_final − U_initial = 0.
The area enclosed by the closed loop in a P-V (pressure-volume) diagram represents the net work done by the system in one complete cycle. For a clockwise cycle, this area equals the work output (positive work done by the gas).
The first law of thermodynamics states that the heat added to a system equals the increase in internal energy plus the work done by the system: Q = ΔU + W. It is the law of conservation of energy applied to thermodynamic systems.
Difference Between Distance and Displacement — With Examples
Difference between distance and displacement — distance is the total path length (scalar), displacement is the shortest straight-line distance from start to end (vector).
Difference Between Evaporation and Boiling
Learn the exact scientific differences between Evaporation and Boiling. Understand surface phenomena vs bulk phenomena, temperature requirements, and cooling effects.
Difference Between g and G (Gravity)
Learn the difference between small 'g' (Acceleration due to gravity) and capital 'G' (Universal Gravitational Constant).
Difference Between Speed and Velocity
Speed is scalar (distance/time); velocity is vector (displacement/time). Speed is always positive; velocity can be negative. Average speed ≥ average velocity.
Difference Between Tungsten and Nichrome
Tungsten: pure metal, mp 3422°C, used in bulb filaments. Nichrome: Ni-Cr alloy, high resistivity 110×10⁻⁸ Ω·m, used in heating elements. Key differences explained.
Turn this guide into revision flashcards, a practice exam, or an AI-generated podcast — free, no signup required.