For a complete thermodynamic cycle, the internal energy change is zero (ΔU = 0) because the system returns to its initial state. By the first law of thermodynamics, the net heat supplied equals the net work done by the system: Q_net = W_net. The net work done in a cycle equals the area enclosed by the P-V diagram.
For a complete thermodynamic cycle, ΔU = 0 (internal energy returns to initial value).
By the first law: Q_net = W_net for a complete cycle.
Net work done = area enclosed by the P-V diagram loop.
Clockwise cycle on P-V diagram → positive net work (heat engine).
Anticlockwise cycle on P-V diagram → negative net work (refrigerator/heat pump).
Heat supplied (Q_absorbed) = W_net + Q_rejected.
Thermal efficiency = W_net / Q_absorbed.
First Law: ΔU = Q − W (or Q = ΔU + W)
For a complete cycle:
Applying the first law: 0 = Q_net − W_net Q_net = W_net
This means:
Conclusion: To find the total heat supplied in a complete cycle, calculate the area enclosed by the cycle on the P-V diagram.
Work done by gas during a process = Area under the P-V curve
For a complete cycle:
For a rectangular cycle (simple example): If pressure goes from P₁ to P₂ and volume goes from V₁ to V₂: W_net = (P₂ − P₁)(V₂ − V₁)
For a circular or irregular cycle: W_net = Area of the closed loop on P-V diagram
Since Q_net = W_net for a complete cycle: Heat supplied = Area of the P-V loop
In a complete cycle:
For a heat engine (clockwise cycle): Efficiency η = W_net / Q_absorbed = 1 − Q_rejected/Q_absorbed
For a refrigerator (anticlockwise cycle): COP = Q_cold / W_net = Q_cold / (Q_hot − Q_cold)
Important: 'Heat supplied' usually refers to Q_absorbed (heat added to the system in the cycle).
For a complete cycle, ΔU = 0, so by the first law (Q = ΔU + W), the net heat supplied equals the net work done: Q_net = W_net. The net work equals the area enclosed by the cycle on the P-V diagram.
Internal energy (U) is a state function — it depends only on the state of the system, not the path taken. In a complete cycle, the system returns to its initial state (same temperature, pressure, and volume), so the change in internal energy ΔU = U_final − U_initial = 0.
The area enclosed by the closed loop in a P-V (pressure-volume) diagram represents the net work done by the system in one complete cycle. For a clockwise cycle, this area equals the work output (positive work done by the gas).
The first law of thermodynamics states that the heat added to a system equals the increase in internal energy plus the work done by the system: Q = ΔU + W. It is the law of conservation of energy applied to thermodynamic systems.
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