Study Guides/Chemistry/Which gas cannot be collected over water
Study Guide · Chemistry

Which Gas Cannot Be Collected Over Water?

In Chemistry practical labs, one common method to collect a pure gas is by displacing water in an inverted jar — called Collection over Water (or Downward Displacement of Water). However, this method only works for certain gases.

Question (Click to Flip)

Can Carbon Dioxide be collected over water?

Answer

CO₂ is slightly soluble in water (it forms carbonic acid), but it is sparingly soluble enough that it can be collected over water for short periods in a lab — though it is more accurately collected by downward displacement of air.

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Key Facts

Hydrogen (H₂), Oxygen (O₂), and Nitrogen (N₂) are the classic gases collected over water because they are nearly insoluble in it.

The Method — and Its Limitation

The 'Collection over Water' method works only when the gas is insoluble or sparingly soluble in water. If a gas dissolves in water, it will simply dissolve into the water rather than displacing it — making collection impossible.

Gases that CANNOT be Collected Over Water

Gases that are highly soluble in water cannot be collected this way:

  • Ammonia (NH₃): Extremely soluble — 700 volumes dissolve in 1 volume of water!
  • Hydrogen Chloride (HCl): Very soluble — forms hydrochloric acid when dissolved
  • Sulphur Dioxide (SO₂): Soluble — forms sulphurous acid
  • Chlorine (Cl₂): Moderately soluble and reacts with water
  • Nitrogen Dioxide (NO₂): Reacts with water

How are Soluble Gases Collected Instead?

  • Ammonia (NH₃): Collected by Upward Displacement of Air (it is lighter than air, density < air)
  • HCl, SO₂: Collected by Downward Displacement of Air (both are heavier than air)

Questions and Answers

Can Carbon Dioxide be collected over water?+

CO₂ is slightly soluble in water (it forms carbonic acid), but it is **sparingly soluble enough** that it can be collected over water for short periods in a lab — though it is more accurately collected by downward displacement of air.

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