Study Guides/Chemistry/Pure Water Composition — Elements and Percentage by Mass
Study Guide · Chemistry

Composition of Pure Water — Formula, Elements and Mass Percentage

Pure water (H₂O) is composed of two elements: hydrogen (H) and oxygen (O). In each water molecule, there are 2 hydrogen atoms and 1 oxygen atom, giving an atom ratio of H:O = 2:1. By mass, water contains 11.11% hydrogen and 88.89% oxygen. This composition is always fixed — obeying the law of constant composition. Water is the most abundant compound on Earth's surface.

Question (Click to Flip)

What is the composition of pure water?

Answer

Pure water (H₂O) is composed of hydrogen and oxygen. It contains 2 hydrogen atoms and 1 oxygen atom per molecule (atom ratio H:O = 2:1). By mass, water is 11.11% hydrogen and 88.89% oxygen (mass ratio H:O = 1:8).

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Key Facts

Pure water formula: H₂O — 2 hydrogen atoms and 1 oxygen atom per molecule.

Mass percentage: 11.11% H and 88.89% O.

Mass ratio H:O = 1:8 (2g H : 16g O in one mole of water).

Molar mass of water = 18 g/mol.

Electrolysis produces H₂:O₂ = 2:1 by volume, confirming water composition.

Water's composition is always fixed — obeys the law of constant composition.

Pure water has melting point 0°C, boiling point 100°C, density 1 g/mL at 4°C.

Water is the universal solvent — dissolves more substances than any other liquid.

Chemical Composition of Water

Molecular formula: H₂O

Atoms per molecule: • 2 hydrogen atoms • 1 oxygen atom • Total: 3 atoms per molecule

Atom ratio: H : O = 2 : 1

Mass composition: • Molar mass of H₂O = 2(1) + 16 = 18 g/mol • Mass of H in H₂O = 2 g/mol • Mass of O in H₂O = 16 g/mol

Percentage by mass: • % H = (2/18) × 100 = 11.11% • % O = (16/18) × 100 = 88.89%

Mass ratio H : O = 2 : 16 = 1 : 8

Therefore: • In 9 g of water: 1 g of H and 8 g of O • In 18 g of water: 2 g of H and 16 g of O

Verification — Electrolysis of Water

The composition of water can be verified by electrolysis:

2H₂O → 2H₂ + O₂ (electrolysis)

Volume ratio: • H₂ : O₂ = 2 : 1 (by volume, at the same temperature and pressure) • This matches the atom ratio in H₂O (2H : 1O)

In electrolysis experiment: • Twice as much hydrogen is collected at the cathode as oxygen at the anode • Confirming H₂O has H and O in 2:1 ratio by volume/moles

This experiment verifies:

  1. Water contains H and O in 2:1 mole ratio
  2. Water is a compound of hydrogen and oxygen
  3. Law of constant composition applies to water — always same ratio

Note: Pure water is required for electrolysis. A few drops of H₂SO₄ or NaOH are added to increase conductivity (ionic conductors), but only water is electrolysed.

Properties of Pure Water

Physical properties: • Molecular formula: H₂O • Molar mass: 18 g/mol • Melting point: 0°C (273.15 K) • Boiling point: 100°C (373.15 K) at 1 atm • Density: 1 g/mL (1 g/cm³) at 4°C (maximum density) • Colourless, odourless, tasteless • pH: 7 (neutral) • Kw = 1.0 × 10⁻¹⁴ at 25°C

Chemical properties: • Amphoteric — acts as acid or base • Universal solvent — dissolves many ionic and polar compounds • Reacts with reactive metals: 2Na + 2H₂O → 2NaOH + H₂↑ • Reacts with basic oxides: CaO + H₂O → Ca(OH)₂ • Reacts with acidic oxides: CO₂ + H₂O → H₂CO₃

Pure water vs tap water: Pure water contains only H₂O; tap water contains dissolved minerals, salts, and gases.

Questions and Answers

What is the composition of pure water?+

Pure water (H₂O) is composed of hydrogen and oxygen. It contains 2 hydrogen atoms and 1 oxygen atom per molecule (atom ratio H:O = 2:1). By mass, water is 11.11% hydrogen and 88.89% oxygen (mass ratio H:O = 1:8).

What percentage of water is hydrogen and oxygen by mass?+

Water contains 11.11% hydrogen and 88.89% oxygen by mass. This is calculated from the molar masses: H₂O = 18 g/mol. Hydrogen contributes 2 g (11.11%) and oxygen contributes 16 g (88.89%) per mole of water.

What is the mass ratio of hydrogen to oxygen in water?+

The mass ratio of hydrogen to oxygen in water is 1:8. In every 9 g of water, 1 g is hydrogen and 8 g is oxygen. This ratio is always fixed regardless of the source of water.

How does electrolysis verify the composition of water?+

Electrolysis of water (2H₂O → 2H₂ + O₂) produces hydrogen and oxygen in a 2:1 volume ratio. This confirms that water contains H and O in a 2:1 mole ratio (as in H₂O), verifying its chemical composition.

What is the molar mass of water?+

The molar mass of water (H₂O) is 18 g/mol. It is calculated as: 2 × mass of H + mass of O = 2(1) + 16 = 18 g/mol.

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