Study Guides/Chemistry/One Mole of Methane — Mass, Atoms, Volume and Molecules
Study Guide · Chemistry

One Mole of Methane — Everything You Need to Know

One mole of methane (CH₄) has a molar mass of 16 g/mol (12 + 4×1 = 16 g). It contains 6.022×10²³ molecules (Avogadro's number), 4 moles of hydrogen atoms (24.088×10²³ H atoms) and 1 mole of carbon atoms. At standard temperature and pressure (STP: 0°C, 1 atm), one mole of any gas (including methane) occupies 22.4 litres.

Question (Click to Flip)

What is the molar mass of methane?

Answer

The molar mass of methane (CH₄) is 16 g/mol. This is calculated as: C = 12 g/mol + 4 × H (4 × 1 g/mol) = 12 + 4 = 16 g/mol.

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Key Facts

Molar mass of methane (CH₄) = 16 g/mol.

1 mole of CH₄ = 16 g = 6.022×10²³ molecules.

1 mole of CH₄ contains 4 moles of H atoms (24.088×10²³ H atoms).

1 mole of CH₄ contains 1 mole of C atoms (6.022×10²³ C atoms).

Volume of 1 mole CH₄ at STP (0°C, 1 atm) = 22.4 L.

Combustion: CH₄ + 2O₂ → CO₂ + 2H₂O, ΔH = −890 kJ/mol.

CH₄ is the lightest alkane and the main component of natural gas (~95%).

1 molecule of CH₄ contains 5 atoms (1C + 4H); 1 mol CH₄ contains 5 mol atoms.

One Mole of Methane — Key Calculations

Methane formula: CH₄ Molar mass calculation: • C: 12 g/mol • H: 1 g/mol × 4 = 4 g/mol • Molar mass of CH₄ = 12 + 4 = 16 g/mol

For ONE mole (1 mol) of CH₄:

  1. Mass = 16 g

  2. Number of molecules: = 1 × Avogadro's number (Nₐ) = 6.022 × 10²³ molecules

  3. Number of C atoms: = 1 × 6.022 × 10²³ = 6.022 × 10²³ atoms (1 C per CH₄ molecule)

  4. Number of H atoms: = 4 × 6.022 × 10²³ = 24.088 × 10²³ atoms (4 H per CH₄ molecule)

  5. Volume at STP (0°C, 1 atm): = 22.4 L (molar volume of any ideal gas at STP)

Mole Concept Applied to Methane

The mole is the SI unit for amount of substance: • 1 mol = 6.022 × 10²³ particles (Avogadro's number)

For CH₄: Atoms per molecule: C=1, H=4, Total=5 atoms per molecule

Atom counting per mole of CH₄: • Total atoms = 5 × Nₐ = 5 × 6.022 × 10²³ = 30.11 × 10²³ atoms • C atoms = 1 × Nₐ = 6.022 × 10²³ • H atoms = 4 × Nₐ = 24.088 × 10²³

Moles of atoms in 1 mol CH₄: • 1 mol of C atoms • 4 mol of H atoms • 5 mol of atoms total

Useful calculations: • 2 mol CH₄ = 32 g, contains 2 × Nₐ molecules • 8 g CH₄ = 8/16 = 0.5 mol = 0.5 × Nₐ molecules • 32 g CH₄ = 2 mol = 44.8 L at STP

Combustion of One Mole of Methane

Combustion equation: CH₄ + 2O₂ → CO₂ + 2H₂O

For 1 mol of CH₄: • Reacts with 2 mol O₂ (= 64 g O₂ = 44.8 L at STP) • Produces 1 mol CO₂ (= 44 g = 22.4 L at STP) • Produces 2 mol H₂O (= 36 g) • Energy released: ~890 kJ/mol (standard enthalpy of combustion)

CH₄ in natural gas: • Natural gas is primarily methane (~95%) • Molar mass: 16 g/mol (lightest hydrocarbon) • Density at STP: 16/22.4 = 0.714 g/L • Less dense than air (average molar mass ~29 g/mol) → natural gas rises if leaked

Physical properties of methane: • Gas at room temperature (bp = −161.5°C) • Colourless, odourless • Greenhouse gas (21× more potent than CO₂ over 100 years)

Questions and Answers

What is the molar mass of methane?+

The molar mass of methane (CH₄) is 16 g/mol. This is calculated as: C = 12 g/mol + 4 × H (4 × 1 g/mol) = 12 + 4 = 16 g/mol.

How many molecules are in one mole of methane?+

One mole of methane (CH₄) contains 6.022 × 10²³ molecules (Avogadro's number). This is true for any substance: 1 mole always contains Avogadro's number (Nₐ) of particles.

How many hydrogen atoms are in one mole of methane?+

One mole of methane (CH₄) contains 4 moles of hydrogen atoms = 4 × 6.022 × 10²³ = 24.088 × 10²³ hydrogen atoms. This is because each CH₄ molecule has 4 hydrogen atoms.

What volume does one mole of methane occupy at STP?+

At STP (0°C and 1 atm), one mole of any ideal gas occupies 22.4 litres. Therefore, one mole of methane (CH₄) occupies 22.4 L at STP.

What is the equation for the combustion of methane?+

CH₄ + 2O₂ → CO₂ + 2H₂O. One mole of methane burns with 2 moles of oxygen to give 1 mole of carbon dioxide and 2 moles of water. The standard enthalpy of combustion of methane is approximately −890 kJ/mol.

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